catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]
نویسندگان
چکیده
In the title coordination polymer, [Cu(NO(3))(2)(C(12)H(12)N(2)O(2))](n), the Cu(II) ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two Cu(II) ions, forming a polymeric chain running along the [101] direction. The three O atoms of the nitrate group are disordered over two positions in a 3:2 ratio.
منابع مشابه
Tetrakis[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]tetrakis(μ-methanolato-κ2 O:O)bis(μ-perchlorato-κ2 O:O′)tetracopper(II) bis(perchlorate)
The title tetra-nuclear Cu(II) complex, [Cu(4)(C(12)H(12)N(2)O(2))(4)(CH(3)O)(4)(ClO(4))(2)](ClO(4))(2), is located around an inversion center. Each Cu(II) atom is coordinated by two cis-O atoms from two bridging methano-late anions and two cis-N atoms from two bridging 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in the basal plane, and is further coordinated by one O atom of the b...
متن کاملPoly[[μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]di-μ-bromido-cadmium]
In the title coordination polymer, [CdBr(2)(C(12)H(12)N(2)O(2))](n), the Cd(II) ion, situated on an inversion centre, is coordinated by four bridging Br atoms and two N atoms from two 1,4-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted octa-hedral geometry. The L ligand, which also lies across an inversion centre, bridges two Cd(II) ions, forming layers parallel to (010).
متن کاملPoly[[μ2-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]di-μ2-chlorido-cadmium]
In the title coordination polymer, [CdCl(2)(C(12)H(12)N(2)O(2))](n), the Cd(II) ion, situated on an inversion center, is coordinated by four bridging Cl atoms and two N atoms from two 1,4-bis-(4,5-dihydro-1,3--oxazol-2-yl)benzene (L) ligands in a distorted octa-hedral geometry. Each L ligand also lies across an inversion center and bridges two Cd(II) ions, forming infinite two-dimensional recta...
متن کاملcatena-Poly[[bis(nitrato-κO)copper(II)]-bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Cu(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the Cu(II) ion lies on an inversion center and is six-coordinated in a Jahn-Teller-distored octa-hedral geometry defined by four N atoms of the pyridine derivative forming a square plane, above and below which are the O atoms of the nitrate anion. The ligand links the metal atoms linto a linear chain running along the a axis. One ...
متن کاملcatena-Poly[[bis(nitrato-κO)cadmium]bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Cd(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the six-coordinated Cd(II) ion is located on an inversion center and has a distorted octa-hedral environment defined by four N atoms from four 1,4-bis-(pyridin-3-ylmeth-oxy)benzene ligands and two O atoms from two nitrate anions. The ligands link the Cd(II) ions into a ribbon-like structure running along [201]. One O atom of the n...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011